Hydrogen atom Chloroiron(III) ion

Navon, G.; Stein, G.
J. Phys. Chem. 70, 3630-3640 (1966)

Reaction: H· + FeCl²⁺ ® Fe²⁺ + Cl^- + H⁺
Reference Reaction: H· + Fe²⁺ ®
Solvent: H₂O

k = 2 × 10⁹(L mol^-1 s^-1), k_reference = 7.5 × 10⁶(L mol^-1 s^-1), pH = 0.8

Experimental method: Discharge
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics in HCl.

Schwarz, H.A.
J. Am. Chem. Soc. 79, 534-536 (1957)

Reaction: H· + FeCl²⁺ ® Fe²⁺ + Cl^- + H⁺
Reference Reaction: H· + O₂ ®
Solvent: H₂O

k/k_reference = 2.3 × 10^-1
k = 2.7 × 10⁹(L mol^-1 s^-1), k_reference = 1.2 × 10¹⁰(L mol^-1 s^-1), pH = 0.8

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics in HCl.