Hydrogen atom Hydroxoiron(III) ion

Baxendale, J.H.; Dixon, R.S.; Stott, D.A.
Trans. Faraday Soc. 64, 2398-2401 (1968)

Reaction: H· + FeOH²⁺ ® Fe²⁺ + H⁺
Reference Reaction: H· + MeOH ®
Solvent: H₂O

pH range 1 to 2, k/k_reference = 480
k = 1.2 × 10⁹(L mol^-1 s^-1), k_reference = 2.6 × 10⁶(L mol^-1 s^-1)

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics in HClO₄.

Navon, G.; Stein, G.
J. Phys. Chem. 70, 3630-3640 (1966)

Reaction: H· + FeOH²⁺ ® Fe²⁺ + H⁺
Reference Reaction: H· + Fe²⁺ ®
Solvent: H₂O

k = 1.2 × 10⁹(L mol^-1 s^-1), k_reference = 7.5 × 10⁶(L mol^-1 s^-1), pH = 0.3

Experimental method: Discharge
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics in HClO₄.