Hydrogen atom Iron(III) ion

Baxendale, J.H.; Dixon, R.S.; Stott, D.A.
Trans. Faraday Soc. 64, 2398-2401 (1968)

Reaction: H· + Fe³⁺ ® Fe²⁺ + H⁺
Reference Reaction: H· + MeOH ®
Solvent: H₂O

pH range 1 to 2, k/k_reference = << 1
k = < 2 × 10⁶(L mol^-1 s^-1), k_reference = 2.6 × 10⁶(L mol^-1 s^-1)

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Limiting value

Competition kinetics in HClO₄ soln.; k(H + FeOH²⁺) >> 500 k(H + Fe³⁺). detd. from pH study.

Navon, G.; Stein, G.
J. Phys. Chem. 70, 3630-3640 (1966)

Reaction: H· + Fe³⁺ ® Fe²⁺ + H⁺
Reference Reaction: H· + Fe²⁺ ®
Solvent: H₂O

k/k_reference = < 1 × 10^-1
k = <7.5 × 10⁵(L mol^-1 s^-1), k_reference = 7.5 × 10⁶(L mol^-1 s^-1), pH = 0.3

Experimental method: Discharge
Analytical method: chemical analysis
Data type: Limiting value

Competition kinetics in HClO₄.