Hydrogen atom Fluorosulfate ion

Klaning, U.K.; Sehested, K.; Appelman, E.H.
Inorg. Chem. 30, 3582-3584 (1991)

Reaction: H· + SO₄F^- ® SO₄·^- + HF
Solvent: H₂O

k = 6 × 10⁸(L mol^-1 s^-1), pH = 1, T = 294K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Obs. SO₄^- formn. in air-free soln. contg. (1.2-6.0) × 10^-3 mol L^-1 SO₄F^- and 0.1 mol L^-1 HClO₄.