Hydrogen atom (R*,R*)-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dienecopper(II) ion

Tait, A.M.; Hoffman, M.Z.; Hayon, E.
Inorg. Chem. 15, 934-939 (1976)

Reaction: H· + Cu(4,11-dieneN₄)²⁺ (R*,R*) ® Cu(4,11-dieneN₄)⁺
Solvent: H₂O

k = > 5 × 10⁹(L mol^-1 s^-1), pH = 1.0

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Limiting value

Product buildup kinetics in Ar-satd. soln. contg. 1 mol L^-1 tert-BuOH.