Hydrogen atom Copper(II) ion

Buxton, G.V.; Greenstock, C.L.; Helman, W.P.; Ross, A.B.
J. Phys. Chem. Ref. Data 17, 513-886 (1988)

Reaction: H· + Cu²⁺ ® Cu⁺ + H⁺
Solvent: H₂O

k = 9.1 × 10⁷(L mol^-1 s^-1)

Data type: Selected or recommended value

Average of 3 values.

Johnson, G.R.A.; Nazhat, N.B.
J. Chem. Soc., Faraday Trans. 1 80, 3455-3462 (1984)

Reaction: H· + Cu²⁺ ® H⁺ + Cu⁺
Reference Reaction: H· + MeOH ®
Solvent: H₂O

k/k_reference = 34
k = 8.8 × 10⁷(L mol^-1 s^-1), k_reference = 2.6 × 10⁶(L mol^-1 s^-1), pH = 1

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics; obs. G(H₂).

Freiberg, M.; Meyerstein, D.
J. Chem. Soc., Faraday Trans. 1 76, 1825-1837 (1980)

Reaction: H· + Cu²⁺ ® Cu⁺ + H⁺
Solvent: H₂O

k = <10⁶(L mol^-1 s^-1)

Suggested that this value is correct based on the presence of Cu⁺ which interferes in most studies.

Baxendale, J.H.; Dixon, R.S.; Stott, D.A.
Trans. Faraday Soc. 64, 2398-2401 (1968)

Reaction: H· + Cu²⁺ ® Cu⁺ + H⁺
Reference Reaction: H· + MeOH ®
Solvent: H₂O

pH range 1 to 2, k/k_reference = 38
k = 9.9 × 10⁷(L mol^-1 s^-1), k_reference = 2.6 × 10⁶(L mol^-1 s^-1)

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics; obs. G(H₂)

Baxendale, J.H.; Hughes, G.
Z. Phys. Chem. (Frankfurt am Main) 14, 306-322 (1958)

Reaction: H· + Cu²⁺ ® Cu⁺ + H⁺
Reference Reaction: H· + MeOH ®
Solvent: H₂O

k/k_reference = 33
k = 8.6 × 10⁷(L mol^-1 s^-1), k_reference = 2.6 × 10⁶(L mol^-1 s^-1), pH = 1

Experimental method: X-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics