Hydrogen atom Chromate(VI) ion

Sutton, J.; Moreau, M.
Proc. of the Second Tihany Symposium on Radiation Chemistry, Dobo, J.; Hedvig, P. (eds.), Publishing House of the Hungarian Acad. of Sci., Budapest, 1967, p.95-103

Reaction: H· + CrO₄^2- ®
Reference Reaction: H· + HCO₂^- ®
Solvent: H₂O

k/k_reference = 30
k = 6.3 × 10⁹(L mol^-1 s^-1), k_reference = 2.1 × 10⁸(L mol^-1 s^-1)

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics

Hayon, E.; Moreau, M.
J. Chim. Phys. 62, 391-394 (1965)

Reaction: H· + CrO₄^2- ®
Reference Reaction: H· + EtOH ®
Solvent: H₂O

k/k_reference = 600
k = 1.0 × 10¹⁰(L mol^-1 s^-1), k_reference = 1.7 × 10⁷(L mol^-1 s^-1), pH ~7

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics