Hydrogen atom Chromium(IV)

Sharpe, P.H.G.; Sehested, K.
Radiat. Phys. Chem. 34, 763-768 (1989)

Reaction: H· + Cr(IV) ®
Solvent: H₂O

k = 1.5 × 10¹⁰(L mol^-1 s^-1), pH = 1, T = 294K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics in Ar-satd. soln. contg. 10^-4 mol L^-1 Cr₂O₇^2- (mostly HCrO₄^-) and 0.1 mol L^-1 HClO₄.