Pentaammine(benzoato)cobalt(III) ion Hydrogen atom

Simic, M.G.; Hoffman, M.Z.; Brezniak, N.V.
J. Am. Chem. Soc. 99, 2166-2172 (1977)

Reaction: Co(NH₃)₅O₂CC₆H₅²⁺ + H· ® Co(NH₃)₅O₂C^·C₆H₆²⁺
Solvent: H₂O

k = 1.5 × 10⁹(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics

Cohen, H.; Meyerstein, D.
J. Am. Chem. Soc. 93, 4179-4183 (1971)

Reaction: H· + Co(NH₃)₅O₂CC₆H₅²⁺ ® Co(NH₃)₅O₂C^·C₆H₆²⁺
Solvent: H₂O

k = 1.6 × 10⁹(L mol^-1 s^-1), pH = 1.0

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 345 nm in Ar-satd. soln. contg. 0.01 mol L^-1 MeOH.