Hydrogen atom Pentaammine(formato)cobalt(III) ion

Shagisultanova, G.A.; Tikhonov, A.S.; Grinkevich, V.A.
High Energy Chem. 7, 49-50 (1973)

Reaction: H· + Co(NH₃)₅O₂CH²⁺ ® [Co(NH₃)₅O₂^·C]²⁺ + H₂
Solvent: H₂O

k = 1.5 × 10⁷(L mol^-1 s^-1), pH = 3.5, T = 277K

Experimental method: Discharge
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Detd. from dose rate of H atoms and amount of redn. product. Unrecommended value because of deficiencies in the method.