Hydrogen atom Trichlorine anion

Gogolev, A.V.; Makarov, I.E.; Pikaev, A.K.
High Energy Chem. 18, 390-395 (1984)

Reaction: H· + Cl₃^- ® Cl₂·^- + H⁺ + Cl^-
Reference Reaction: H· + O₂ ®
Solvent: H₂O

k = 3 × 10¹⁰(L mol^-1 s^-1), k_reference = 1.2 × 10¹⁰(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics in 1 mol L^-1 HCl soln. contg. chlorine and oxygen; estd. from G(Cl₂^-); k = 2 × 10¹⁰ in 2 mol L^-1 HCl.