Hydrogen atom Thiocyanate ion

Elliot, A.J.; Geertsen, S.; Buxton, G.V.
J. Chem. Soc., Faraday Trans. 1 84, 1101-1112 (1988)

Reaction: H· + SCN^- ®
Solvent: H₂O

k = 2.3 × 10⁸(L mol^-1 s^-1), pH = 1

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 425 nm in Ar-satd. soln. contg. 0.1 mol L^-1 HClO₄ and 2.5-7.5 × 10^-2 mol L^-1 thiocyanate ion.