Hydrogen atom Carbon monoxide

Raef, Y.; Swallow, A.J.
Trans. Faraday Soc. 59, 1631-1640 (1963)

Reaction: H· + CO ® ·CHO
Reference Reaction: H· + Fe²⁺ ®
Solvent: H₂O

k/k_reference = 2.2
k = 1.7 × 10⁷(L mol^-1 s^-1), k_reference = 7.5 × 10⁶(L mol^-1 s^-1), pH = 1.2

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics Discrepancy with other reported data. No recommendation.

Raef, Y.; Swallow, A.J.
Trans. Faraday Soc. 59, 1631-1640 (1963)

Reaction: H· + CO ® ·CHO
Reference Reaction: H· + CH₂(OH)₂ ®
Solvent: H₂O

k/k_reference = 10
k = 4.9 × 10⁷(L mol^-1 s^-1), k_reference = 3.3 × 10⁶(L mol^-1 s^-1), pH = 1

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics Discrepancy with other reported data. No recommendation.