Hydrated electron Hexaamminecobalt(III) ion

Waltz, W.L.; Pearson, R.G.
J. Phys. Chem. 73, 1941-1952 (1969)

Reaction: e_aq^- + Co(NH₃)₆³⁺ ®
Solvent: H₂O

k = 8.8 × 10¹⁰(L mol^-1 s^-1), pH ~7

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 690 nm, counterion Cl^-; soln. contains < 10^-3 mol L^-1 H₂.

Meyerstein, D.; Mulac, W.A.
J. Phys. Chem. 73, 1091-1095 (1969)

Reaction: e_aq^- + Co(NH₃)₆³⁺ ®
Solvent: H₂O

pH range 5 to 6
k = 8.5 × 10¹⁰(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 575 nm, counterion ClO₄^-.

Anbar, M.; Hart, E.J.
Adv. Chem. Ser. 81, 79-94 (1968)

Reaction: e_aq^- + Co(NH₃)₆³⁺ ®
Solvent: H₂O

k = 8.2 × 10¹⁰(L mol^-1 s^-1), ionic strength ®0, pH = 6.7

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics; counterion ClO₄^-; I = 6 × 10^-5

Anbar, M.; Hart, E.J.
J. Phys. Chem. 69, 973-977 (1965)

Reaction: e_aq^- + Co(NH₃)₆³⁺ ®
Solvent: H₂O

k = 9.0 × 10¹⁰(L mol^-1 s^-1), pH = 11.1

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics; counterion ClO₄^-; soln. contains 0.2 mol L^-1 NH₃.

Baxendale, J.H.; Fielden, E.M.; Keene, J.P.
Proc. R. Soc. London, Ser. A 286, 320-336 (1965)

Reaction: e_aq^- + Co(NH₃)₆³⁺ ®
Solvent: H₂O

Activation energy = 18(kJ mol^-1), Log(A) = 14.082, Temperature range 294 to 351 K
k = 9.0 × 10¹⁰(L mol^-1 s^-1), T = 294K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics; counterion ClO₄^-.