Hydrated electron 5,7,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,14-dienecobalt(II) ion

Tait, A.M.; Hoffman, M.Z.; Hayon, E.
J. Am. Chem. Soc. 98, 86-93 (1976)

Reaction: e_aq^- + Co(4,14-dieneN₄)²⁺ ®
Solvent: H₂O

pH range 6 to 10
k = 3.4 × 10¹⁰(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 700 and 500 nm in Ar-satd. soln. contg. 1 mol L^-1 tert-BuOH and phosphate or borate buffer; pK of the diene 10, 11.