Hydrated electron N-rac-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dienecobalt(II) ion

Elroi, H.; Meyerstein, D.
J. Am. Chem. Soc. 100, 5540-5548 (1978)

Reaction: e_aq^- + N-rac-Co(4,11-dieneN₄)²⁺ ® Co(4,11-dieneN₄)⁺
Solvent: H₂O

k = 4.4 × 10¹⁰(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 600 nm.

Tait, A.M.; Hoffman, M.Z.; Hayon, E.
J. Am. Chem. Soc. 98, 86-93 (1976)

Reaction: e_aq^- + N-rac-Co(4,11-dieneN₄)²⁺ ® Co(4,11-dieneN₄)⁺
Solvent: H₂O

pH range 6 to 10
k = 4.4 × 10¹⁰(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 700 and 500 nm in Ar-satd. soln. contg. 1 mol L^-1 tert-BuOH and phosphate or borate buffer.