Hydrated electron Chlorate ion

Buxton, G.V.; Subhani, M.S.
J. Chem. Soc., Faraday Trans. 1 68, 947-957 (1972)

Reaction: e_aq^- + ClO₃^- ®
Solvent: H₂O

k < 1 × 10⁶(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Limiting value

Solute has no effect on d.k. of e_aq^-.

Cercek, B.
Nature (London) 223, 491-492 (1969)

Reaction: e_aq^- + ClO₃^- ®
Solvent: H₂O

Activation energy = 13(kJ mol^-1), Log(A) = 10.732, Temperature range 288 to 353 K
k = 2.2 × 10⁸(L mol^-1 s^-1), T = 293K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 650 nm.