Hydrated electron Hypochlorite ion

Buxton, G.V.
Unpublished data (Deposited in the RCDC), 1987, 2p.

Reaction: e_aq^- + ClO^- ® O·^- + Cl^-
Solvent: H₂O

k = 7.3 × 10⁹(L mol^-1 s^-1), ionic strength ®0, pH = 9.2

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 700 nm in soln. contg. 0.01 mol L^-1 borax and (1-6) × 10^-4 mol L^-1 ClO^-1; k_obs = 9.8 × 10⁹.

Anbar, M.; Hart, E.J.
Adv. Chem. Ser. 81, 79-94 (1968)

Reaction: e_aq^- + ClO^- ® Cl^- + O·^-
Solvent: H₂O

k = 7.0 × 10⁹(L mol^-1 s^-1), ionic strength ®0, pH = 10.2
k = 7.2 × 10⁹(L mol^-1 s^-1), ionic strength = 0.001

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics; counterion Na⁺.