Hydrated electron Dicarbonatocerate(IV)

Gogolev, A.V.; Shilov, V.P.; Fedoseev, A.M.; Pikaev, A.K.
Bull. Acad. Sci. USSR, Div. Chem. Sci. 39, 21-25 (1990)

Reaction: e_aq^- + Ce(CO₃)₂ ® Ce(CO₃)₂^-
Solvent: H₂O

k = 5.0 × 10⁹(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 700 nm in soln. contg. 1.0 mol L^-1 K₂CO₃; k = 3.5 and 4.0 × 10⁹ at 6.0 and 3.0 mol L^-1 K₂CO₃, resp.