Hydrated electron 5,10,15,20-Tetrakis(1-methylpyridinium-4-yl)porphinatocadmium(II) ion

Harriman, A.; Richoux, M.C.; Neta, P.
J. Phys. Chem. 87, 4957-4965 (1983)

Reaction: e_aq^- + CdTMpyP⁴⁺ ® [CdTMpyP]·³⁺
Solvent: H₂O

k = 1 × 10¹⁰(L mol^-1 s^-1), pH = 7

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics in soln. contg. 2-PrOH, initial fast reaction followed by slow grow-in due to 2-PrOH radical.