Hydrated electron Ethylenediaminetetraacetatocadmate(II) ion

Bruitenhuis, R.; Bakker, C.M.N.; Stock, F.R.; Louwrier, P.W.F.
Radiochim. Acta , 189-192 (1977)

Reaction: e_aq^- + CdEDTA^2- ® CdEDTA^3-
Solvent: H₂O

k = 2.0 × 10⁸(L mol^-1 s^-1), ionic strength = 0.016, pH = 11.5, T = 293K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics in buffered soln. contg. 0.5% n-BuOH; product identified in [80BUI/BAK].

Anbar, M.; Meyerstein, D.
Trans. Faraday Soc. 65, 1812-1817 (1969)

Reaction: e_aq^- + CdEDTA^2- ® CdEDTA^3-
Solvent: H₂O

pH range 11 to 12
k = 3.9 × 10⁸(L mol^-1 s^-1), ionic strength = 0.2

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 575 nm; counterion Na⁺.