Hydrated electron Cadmium(II) ion

Lardinois, P.; Rebena, I.; Hickel, B.
New J. Chem. 12, 21-25 (1988)

Reaction: e_aq^- + Cd²⁺ ® Cd⁺
Solvent: H₂O

k = 4.8 × 10¹⁰(L mol^-1 s^-1), ionic strength ®0

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 500 nm in soln. contg. 0.001 mol L^-1 Cd(Cl)₄)₂ and 0.1 mol L^-1 tert-BuOH.

Shiraishi, H.; Katsumura, Y.; Hiroishi, D.; Ishigure, K.; Washio, M.
J. Phys. Chem. 92, 3011-3017 (1988)

Reaction: e_aq^- + Cd²⁺ ® Cd⁺
Solvent: H₂O

Activation energy = 16(kJ mol^-1), Log(A) = 13.436, Temperature range 293 to 523 K
k = 4.7 × 10¹⁰(L mol^-1 s^-1), T = 293K
k = 5.5 × 10¹¹(L mol^-1 s^-1), T = 473K
k = ~8.1 × 10¹¹(L mol^-1 s^-1), T = 523K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 300 nm in CdSO₄ soln. (2 and 4 × 10^-4 mol L^-1).

Buxton, G.V.; Sellers, R.M.
J. Chem. Soc., Faraday Trans. 1 71, 558-567 (1975)

Reaction: e_aq^- + Cd²⁺ ® Cd⁺
Solvent: H₂O

k = 4.8 × 10¹⁰(L mol^-1 s^-1), ionic strength = 1.8 × 10^-3, pH = 6.1

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 600 nm; counter ion SO₄^2-.

Hentz, R.R.; Farhataziz; Hansen, E.M.
J. Chem. Phys. 56, 4485-4488 (1972)

Reaction: e_aq^- + Cd²⁺ ® Cd⁺
Solvent: H₂O

k = 6.0 × 10¹⁰(L mol^-1 s^-1), pH = 6.1

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics; k also detd. at 6.4 kbar (6.4 × 10⁸ N/m²); counter ion SO₄^2-.

Peled, E.; Czapski, G.
J. Phys. Chem. 74, 2903-2911 (1970)

Reaction: e_aq^- + Cd²⁺ ® Cd⁺
Solvent: H₂O

k = 6.4 × 10¹⁰(L mol^-1 s^-1), ionic strength ®0, pH = 4.4

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 550 nm in soln. contg. 0.001 mol L^-1 EtOH and 1 and 0.1 mol L^-1 CdSO₄

Meyerstein, D.; Mulac, W.A.
Trans. Faraday Soc. 65, 1818-1826 (1969)

Reaction: e_aq^- + Cd²⁺ ® Cd⁺
Solvent: H₂O

k = 5.1 × 10¹⁰(L mol^-1 s^-1), ionic strength = 4.0 × 10^-5, pH = 6.0

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 575 nm

Baxendale, J.H.; Fielden, E.M.; Keene, J.P.
Proc. R. Soc. London, Ser. A 286, 320-336 (1965)

Reaction: e_aq^- + Cd²⁺ ® Cd⁺
Solvent: H₂O

k = 5.2 × 10¹⁰(L mol^-1 s^-1), pH = 7

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics; counterion Cl^- or ClO₄^-.

Anbar, M.; Hart, E.J.
J. Phys. Chem. 69, 973-977 (1965)

Reaction: e_aq^- + Cd²⁺ ® Cd⁺
Solvent: H₂O

k = 4.8 × 10¹⁰(L mol^-1 s^-1), pH = 6.5

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics; counterion SO₄^2-.