Hydrated electron Carbon monoxide

Derai, R.; Remita, H.; Delcourt, M.O.
Radiat. Phys. Chem. 38, 483-486 (1991)

Reaction: e_aq^- + CO ® CO^-
Solvent: H₂O

k = 1.6 × 10⁹(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics in CO-satd. soln. contg. 0.2 mol L^-1 2-PrOH and varied concn. of Rh^II acetate dimer, extrapolated to zero [Rh^II].

Ho, K.; Klapper, M.H.; Dorfman, L.M.
J. Biol. Chem. 253, 238-241 (1978)

Reaction: e_aq^- + CO ® CO^-
Solvent: H₂O

k = 1.6 × 10⁹(L mol^-1 s^-1), pH = 6.2

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics in unbuffered soln.; same result in soln. contg. 0.1 mol L^-1 NaCl and 0.1 mol L^-1 MeOH.

Razem, D.; Hamill, W.H.
J. Phys. Chem. 81, 1625-1631 (1977)

Reaction: e_aq^- + CO ® CO^-
Solvent: H₂O

k = 1.8 × 10⁹(L mol^-1 s^-1), T = 293K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics