Hydrated electron Bromate ion

Peled, E.; Czapski, G.
J. Phys. Chem. 74, 2903-2911 (1970)

Reaction: e_aq^- + BrO₃^- ® BrO₃^2-
Solvent: H₂O

k = 3.4 × 10⁹(L mol^-1 s^-1), ionic strength ®0, pH ~7

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 550 nm in soln. contg. 10^-1 mol L^-1 EtOH and 0.01, 0.1 and 1 mol L^-1 NaBrO₃

Cercek, B.
Nature (London) 223, 491-492 (1969)

Reaction: e_aq^- + BrO₃^- ® BrO₃^2-
Solvent: H₂O

Activation energy = 19(kJ mol^-1), Log(A) = 13.280, Temperature range 288 to 353 K
k = 7.8 × 10⁹(L mol^-1 s^-1), T = 293K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 650 nm.

Buxton, G.V.; Dainton, F.S.
Proc. R. Soc. London, Ser. A 304, 427-439 (1968)

Reaction: e_aq^- + BrO₃^- ® BrO₃^2-
Solvent: H₂O

k = 2.3 × 10⁹(L mol^-1 s^-1), ionic strength ®0, pH = 13
k = 4.1 × 10⁹(L mol^-1 s^-1), ionic strength = 0.1

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 600 nm; counterion K⁺.

Anbar, M.; Hart, E.J.
J. Phys. Chem. 69, 973-977 (1965)

Reaction: e_aq^- + BrO₃^- ® BrO₃^2-
Solvent: H₂O

k = 2.1 × 10⁹(L mol^-1 s^-1), pH = 7

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics; counterion K⁺.