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Hydrated electron
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Buxton, G.V.; Dainton, F.S.
Proc. R. Soc. London, Ser. A 304, 427-439 (1968)
Reaction: eaq- + BrO2- ®
BrO + O2-
Solvent: H2O
k = 1.1 × 1010(L mol-1 s-1), ionic strength ®0, pH = 13
k = 1.8 × 1010(L mol-1 s-1), ionic strength = 0.1
Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Decay kinetics at 600 nm; counterions Na+, BrO3-, Br-.