Hydrated electron Bromocuprate(I)

Stevenson, K.L.; Berger, R.M.; Grush, M.M.; Stayanoff, J.C.; Horvath, A.; Horvath, O.
J. Photochem. Photobiol., A 60, 215-227 (1991)

Reaction: e_aq^- + Bromocuprate(I) ®
Solvent: H₂O

k = 7.5 × 10⁹(L mol^-1 s^-1), ionic strength = 3

Experimental method: Flash photolysis/photoionization
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Excitation wavelength: 266 nm

Decay kinetics at 700 nm in soln. contg. 2.5 mol L^-1 NaClO₄, (0.5-4) × 10^-4 mol L^-1 CuBr and 0.5 mol L^-1 NaBr.