Hydrated electron Hexafluoroarsenate(V) ion

Proesch, U.; Helmstreit, W.; Kolditz, L.
Isotopenpraxis 12, 288-291 (1976)

Reaction: e_aq^- + AsF₆^- ® AsF₆^2-
Solvent: H₂O

k = 1 × 10¹⁰(L mol^-1 s^-1), pH = 9.2

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 720 nm, as well as p.b.k. at 310 nm; contains 10^-2 mol L^-1 borax buffer.

Anbar, M.; Hart, E.J.
J. Phys. Chem. 69, 973-977 (1965)

Reaction: e_aq^- + AsF₆^- ® AsF₆^2-
Solvent: H₂O

k = 9.0 × 10⁹(L mol^-1 s^-1), pH = 7.0

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics