Hydrated electron Dioxoamericium(VI) ion

Gordon, S.; Mulac, W.A.; Schmidt, K.H.; Sjoblom, R.K.; Sullivan, J.C.
Inorg. Chem. 17, 294-296 (1978)

Reaction: e_aq^- + AmO₂²⁺ ® AmO₂⁺
Solvent: H₂O

k = 3.9 × 10¹⁰(L mol^-1 s^-1), ionic strength = 0.11, pH = 6.0, T = 296K
k = 3.1 × 10¹⁰(L mol^-1 s^-1), pH = 5.3

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 650 nm in He-satd. soln. contg. 0.1 mol L^-1 tert-BuOH and 0.11 mol L^-1 LiClO₄.